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量子热力学循环与量子热机。

Quantum thermodynamic cycles and quantum heat engines.

作者信息

Quan H T, Liu Yu-xi, Sun C P, Nori Franco

机构信息

Frontier Research System, Institute of Physical and Chemical Research (RIKEN), Wako-shi, Saitama 351-0198, Japan.

出版信息

Phys Rev E Stat Nonlin Soft Matter Phys. 2007 Sep;76(3 Pt 1):031105. doi: 10.1103/PhysRevE.76.031105. Epub 2007 Sep 7.

Abstract

In order to describe quantum heat engines, here we systematically study isothermal and isochoric processes for quantum thermodynamic cycles. Based on these results the quantum versions of both the Carnot heat engine and the Otto heat engine are defined without ambiguities. We also study the properties of quantum Carnot and Otto heat engines in comparison with their classical counterparts. Relations and mappings between these two quantum heat engines are also investigated by considering their respective quantum thermodynamic processes. In addition, we discuss the role of Maxwell's demon in quantum thermodynamic cycles. We find that there is no violation of the second law, even in the existence of such a demon, when the demon is included correctly as part of the working substance of the heat engine.

摘要

为了描述量子热机,在此我们系统地研究量子热力学循环的等温过程和等容过程。基于这些结果,卡诺热机和奥托热机的量子版本被明确地定义。我们还将量子卡诺热机和奥托热机的性质与其经典对应物进行了比较研究。通过考虑它们各自的量子热力学过程,还研究了这两种量子热机之间的关系和映射。此外,我们讨论了麦克斯韦妖在量子热力学循环中的作用。我们发现,当妖被正确地作为热机工作物质的一部分包含在内时,即使存在这样的妖也不会违反第二定律。

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