Yuan Guang-Cai, Xu Zheng, Zhang Fu-Jun, Wang Yong, Zhao De-Wei, Xu Hong-Hua
Institute of Optoelectronics Technology, Beijing Jiaotong University, Key Laboratory of Luminescence and Optical Information, Ministry of Education, Beijing 100044, China.
Guang Pu Xue Yu Guang Pu Fen Xi. 2007 Jul;27(7):1263-6.
ZnO films were deposited on different structural substrate by rf-reactive Magnetron sputtering. The optical characteristics of ZnO films were studied by X-ray diffraction and optical transmission spectrum. The ZnO films deposited on the Al2 O3 / AlN compound substrate had better crystallized and had a higher transmittance compared to the ones on AlN substrate. The optical characteristics of ZnO films were studied after all samples with a series of annealing temperature from 200 degrees C to 500 degrees C. When the annealing temperature was 400 degrees C, crystallization and c-axis (002) oriented of the ZnO film got best, and average optical transmittance reached 88% in the range visible light. While annealing temperature went beyond 450 degrees C, the crystallized structure of ZnO films was broken; the distance between O and Zn atoms became bigger. The authors found that the higher annealing temperature make against crystallization of ZnO thin film and increased density of defect states and dispersion mechanisms and reduced optical characteristics of ZnO film, and average optical transmittance of ZnO films reached 80% in the range of visible light at 500 degrees C.
通过射频反应磁控溅射在不同结构的衬底上沉积氧化锌薄膜。采用X射线衍射和光学透射光谱研究了氧化锌薄膜的光学特性。与在氮化铝衬底上沉积的氧化锌薄膜相比,沉积在氧化铝/氮化铝复合衬底上的氧化锌薄膜结晶性更好,且具有更高的透过率。对所有样品在200℃至500℃的一系列退火温度下进行处理后,研究了氧化锌薄膜的光学特性。当退火温度为400℃时,氧化锌薄膜的结晶度和c轴(002)取向最佳,在可见光范围内平均光学透过率达到88%。当退火温度超过450℃时,氧化锌薄膜的结晶结构被破坏;氧原子和锌原子之间的距离变大。作者发现,较高的退火温度不利于氧化锌薄膜的结晶,增加了缺陷态密度和散射机制,降低了氧化锌薄膜的光学特性,在500℃时,氧化锌薄膜在可见光范围内的平均光学透过率达到80%。