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镍催化α,β-不饱和酯和酰胺与双(频哪醇)二硼的β-硼化反应

Nickel-catalyzed beta-boration of alpha,beta-unsaturated esters and amides with bis(pinacolato)diboron.

作者信息

Hirano Koji, Yorimitsu Hideki, Oshima Koichiro

机构信息

Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.

出版信息

Org Lett. 2007 Nov 22;9(24):5031-3. doi: 10.1021/ol702254g. Epub 2007 Nov 1.

DOI:10.1021/ol702254g
PMID:17973483
Abstract

A nickel catalyst system for beta-boration of alpha,beta-unsaturated esters and amides with bis(pinacolato)diboron has been developed. The catalyst system enables the boration of di-, tri-, and tetrasubstituted substrates in good yields.

摘要

已开发出一种用于用双(频哪醇合)二硼对α,β-不饱和酯和酰胺进行β-硼化反应的镍催化剂体系。该催化剂体系能使二取代、三取代和四取代底物以良好的产率进行硼化反应。

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