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Catalytic C-C coupling via transfer hydrogenation: reverse prenylation, crotylation, and allylation from the alcohol or aldehyde oxidation level.

作者信息

Bower John F, Skucas Eduardas, Patman Ryan L, Krische Michael J

机构信息

University of Texas at Austin, Department of Chemistry and Biochemistry, Austin, Texas 78712, USA.

出版信息

J Am Chem Soc. 2007 Dec 12;129(49):15134-5. doi: 10.1021/ja077389b. Epub 2007 Nov 17.

DOI:10.1021/ja077389b
PMID:18020342
Abstract
摘要

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Catalytic C-C coupling via transfer hydrogenation: reverse prenylation, crotylation, and allylation from the alcohol or aldehyde oxidation level.通过转移氢化实现催化碳-碳偶联：从醇或醛氧化水平进行反向异戊烯基化、巴豆酰化和烯丙基化。
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Enantioselective iridium-catalyzed carbonyl allylation from the alcohol or aldehyde oxidation level via transfer hydrogenative coupling of allyl acetate: departure from chirally modified allyl metal reagents in carbonyl addition.通过乙酸烯丙酯的转移氢化偶联，从醇或醛氧化水平进行对映选择性铱催化的羰基烯丙基化反应：在羰基加成反应中背离手性修饰的烯丙基金属试剂。
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4
Enantioselective iridium-catalyzed carbonyl allylation from the alcohol oxidation level via transfer hydrogenation: minimizing pre-activation for synthetic efficiency.手性铱催化的羰基烯丙基化反应：通过转移氢化从醇氧化水平实现对映选择性，最小化预活化以提高合成效率。
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anti-Diastereo- and enantioselective carbonyl crotylation from the alcohol or aldehyde oxidation level employing a cyclometallated iridium catalyst: alpha-methyl allyl acetate as a surrogate to preformed crotylmetal reagents.使用环金属化铱催化剂从醇或醛氧化水平进行反非对映和对映选择性羰基巴豆酰化反应：乙酸α-甲基烯丙酯作为预制巴豆基金属试剂的替代物。
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Enantioselective iridium-catalyzed carbonyl allylation from the alcohol or aldehyde oxidation level using allyl acetate as an allyl metal surrogate.使用乙酸烯丙酯作为烯丙基金属替代物，从醇或醛氧化水平进行对映选择性铱催化的羰基烯丙基化反应。
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Enantioselective carbonyl reverse prenylation from the alcohol or aldehyde oxidation level employing 1,1-dimethylallene as the prenyl donor.以1,1-二甲基丙二烯作为异戊烯基供体，从醇或醛氧化水平进行对映选择性羰基反向异戊烯基化反应。
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Iridium-catalyzed anti-diastereo- and enantioselective carbonyl (trimethylsilyl)allylation from the alcohol or aldehyde oxidation level.铱催化的反非对映和对映选择性羰基（三甲基硅基）烯丙基化反应来自醇或醛的氧化水平。
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