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连续流纳米技术:操控银纳米颗粒的尺寸、形状、团聚、缺陷和相

Continuous flow nano-technology: manipulating the size, shape, agglomeration, defects and phases of silver nano-particles.

作者信息

Iyer K Swaminathan, Raston Colin L, Saunders Martin

机构信息

Centre for Strategic Nano-fabrication, School of Biomedical, Biomolecular and Chemical Sciences, The University of Western Australia, Crawley, WA 6009, Australia.

出版信息

Lab Chip. 2007 Dec;7(12):1800-5. doi: 10.1039/b709524d. Epub 2007 Sep 19.

Abstract

Spinning disc processing (SDP) is an instantaneously scalable, continuous flow and high throughput flash nano-fabrication technology which embraces green chemistry metrics. It has been used to prepare silver nano-particles with remarkable control in size (5-200 nm), shape (spheroidal, acicular or agglomerate rosettes), surface characteristics, and phase (cubic versus hexagonal), along with imparting defects for particles >10 nm diameters. The control is associated with changing the nature of the stabilising surfactant (respectively, starch, polyethylene glycol and poly(4-vinylpyridine)), the concentration of the reactants, and flow rates.

摘要

旋转盘处理(SDP)是一种即时可扩展、连续流动且高通量的闪速纳米制造技术,符合绿色化学标准。它已被用于制备银纳米颗粒,在尺寸(5-200纳米)、形状(球形、针状或团聚玫瑰花状)、表面特性和相(立方相与六方相)方面具有显著的可控性,同时还能为直径大于10纳米的颗粒引入缺陷。这种可控性与改变稳定表面活性剂的性质(分别为淀粉、聚乙二醇和聚(4-乙烯基吡啶))、反应物浓度和流速有关。

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