• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

一种吡唑盐支撑的Fe(3)(μ(3)-O)核：结构、光谱、电化学和磁性研究。

A pyrazolate-supported Fe(3)(mu(3)-O) core: structural, spectroscopic, electrochemical, and magnetic study.

作者信息

Piñero Dalice, Baran Peter, Boca Roman, Herchel Radovan, Klein Michael, Raptis Raphael G, Renz Franz, Sanakis Yiannis

机构信息

Department of Chemistry and the Institute of Functional Nanomaterials, University of Puerto Rico, San Juan, PR, Puerto Rico.

出版信息

Inorg Chem. 2007 Dec 24;46(26):10981-9. doi: 10.1021/ic0701460. Epub 2007 Nov 29.

DOI:10.1021/ic0701460
PMID:18044951
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2597296/
Abstract

A comparison is made between the structural, spectroscopic, electrochemical, and magnetic properties of pyrazolate versus carboxylate complexes [Fe3(mu3(mu3O)(mu-LL)6Cl3]2- containing the Fe3(mu3-O)-motif. While the Fe3(mu3-O)-cores are structurally indistinguishable in the two types of complexes, their magnetic properties deviate from the expected values as a result of a through-pyrazole contribution to the overall antiferromagnetic exchange with J1/hc = -80.1 cm(-1) and J2/hc = -72.4 cm(-1), or J1/hc = 70.6 cm(-1) and J2/hc = -80.8 cm(-1), (Hex = -J1(S1S2 + S2S3) - J2S1S3). The magnetic properties of the pyrazolate complexes are further tuned by an antisymmetric exchange interaction term.

摘要

对含有Fe3(μ3 - O)结构基序的吡唑酸盐与羧酸盐配合物[Fe3(μ3(μ3O)(μ - LL)6Cl3]2 - 的结构、光谱、电化学和磁性进行了比较。虽然在这两种配合物中Fe3(μ3 - O)核心在结构上难以区分，但由于吡唑对整体反铁磁交换的贡献，其磁性偏离了预期值，其中J1/hc = - 80.1 cm(-1)，J2/hc = - 72.4 cm(-1)，或J1/hc = 70.6 cm(-1)，J2/hc = - 80.8 cm(-1)，(Hex = - J1(S1S2 + S2S3) - J2S1S3)。吡唑酸盐配合物的磁性通过反对称交换相互作用项进一步调节。

相似文献

1
A pyrazolate-supported Fe(3)(mu(3)-O) core: structural, spectroscopic, electrochemical, and magnetic study.一种吡唑盐支撑的Fe(3)(μ(3)-O)核：结构、光谱、电化学和磁性研究。
Inorg Chem. 2007 Dec 24;46(26):10981-9. doi: 10.1021/ic0701460. Epub 2007 Nov 29.
2
Theoretical description of the magnetic properties of μ3-hydroxo bridged trinuclear copper(II) complexes.μ3-羟桥基三核铜（II）配合物磁性的理论描述。
J Mol Model. 2013 Jul;19(7):2835-44. doi: 10.1007/s00894-012-1696-5. Epub 2012 Dec 7.
3
Synthesis, crystal structure, and magnetic studies of oxo-centered trinuclear chromium(III) complexes: [Cr(3)(mu(3)-O)(mu(2)-PhCOO)(6)(H(2)O)(3)]NO(3). 4H(2)O.2CH(3)OH, a case of spin-frustrated system, and [Cr(3)(mu(3)-O)- (mu(2)-PhCOO)(2)(mu(2)-OCH(2)CH(3))(2)(bpy)(2)(NCS )(3)], a new type of [Cr(3)O] core.以氧为中心的三核铬（III）配合物的合成、晶体结构及磁性研究：[Cr(3)(μ(3)-O)(μ(2)-PhCOO)(6)(H(2)O)(3)]NO(3). 4H(2)O.2CH(3)OH，一个自旋受挫体系的实例，以及[Cr(3)(μ(3)-O)-(μ(2)-PhCOO)(2)(μ(2)-OCH(2)CH(3))(2)(bpy)(2)(NCS )(3)]，一种新型的[Cr(3)O]核 。
Inorg Chem. 2007 Dec 24;46(26):11017-24. doi: 10.1021/ic700606e. Epub 2007 Nov 16.
4
A planar carboxylate-rich tetraironII complex and its conversion to linear triironII and paddlewheel diironII complexes.一种富含平面羧酸盐的四铁（II）配合物及其向线性三铁（II）和桨轮二铁（II）配合物的转化。
Inorg Chem. 2007 Dec 10;46(25):10754-70. doi: 10.1021/ic701663j. Epub 2007 Nov 13.
5
Mechanistic and energetic aspects of the thermal and photochemical redox chemistry of the octanuclear cubane complexes, Fe(III)(8)(mu(4)-O(4))(mu-pyrazolate)(12)X(4) (X = Cl or Br).八核立方烷配合物 Fe(III)(8)(mu(4)-O(4))(mu-吡唑)(12)X(4)（X = Cl 或 Br）的热和光化学氧化还原化学的机理和能量学方面。
J Phys Chem A. 2010 May 13;114(18):5702-9. doi: 10.1021/jp911644e.
6
Multireversible redox processes in pentanuclear bis(triple-helical) manganese complexes featuring an oxo-centered triangular {Mn(II)2Mn(III)(μ3-O)}5+ or {Mn(II)Mn(III)2(μ3-O)}6+ core wrapped by two {Mn(II)2(bpp)3}-.五核双（三联吡啶）锰配合物中的多可逆氧化还原过程，其特征为一个以氧为中心的三角形{Mn(II)2Mn(III)(μ3-O)}5+或{Mn(II)Mn(III)2(μ3-O)}6+核，被两个{Mn(II)2(bpp)3}-所包裹。
Inorg Chem. 2011 Sep 5;50(17):8427-36. doi: 10.1021/ic201009z. Epub 2011 Aug 3.
7
Studies of iron(II) and iron(III) complexes with fac-N2O, cis-N2O2 and N2O3 donor ligands: models for the 2-His 1-carboxylate motif of non-heme iron monooxygenases.研究具有 fac-N2O、cis-N2O2 和 N2O3 供体配体的铁(II)和铁(III)配合物：非血红素铁单加氧酶 2-His1-羧酸盐基序的模型。
Dalton Trans. 2012 May 14;41(18):5662-77. doi: 10.1039/c2dt11096b. Epub 2012 Mar 21.
8
Novel heterometallic Schiff base complexes featuring unusual tetranuclear {Co(III)2Fe(III)2(μ-O)6} and octanuclear {Co(III)4Fe(III)4(μ-O)14} cores: direct synthesis, crystal structures, and magnetic properties.新型杂核希夫碱配合物具有不寻常的四核{Co(III)2Fe(III)2(μ-O)6}和八核{Co(III)4Fe(III)4(μ-O)14}核：直接合成、晶体结构和磁性。
Inorg Chem. 2012 Jan 2;51(1):386-96. doi: 10.1021/ic2017962. Epub 2011 Nov 30.
9
Antisymmetric exchange in triangular tricopper(II) complexes: correlation among structural, magnetic, and electron paramagnetic resonance parameters.三角形三铜(II)配合物中的反称交换：结构、磁性和电子顺磁共振参数之间的相关性。
Inorg Chem. 2012 Jan 16;51(2):985-1001. doi: 10.1021/ic2020034. Epub 2011 Dec 23.
10
Solution and solid state characterization of oxo-centered trinuclear iron(III) acetate complexes [Fe3(μ3-O)(μ-OAc)6(L)3]+.[Fe3(μ3-O)(μ-OAc)6(L)3]+型多核铁(III)醋酸盐配合物的溶液和固态结构表征。
Spectrochim Acta A Mol Biomol Spectrosc. 2012 Jan;85(1):17-24. doi: 10.1016/j.saa.2011.08.034. Epub 2011 Sep 21.

引用本文的文献

1
The Ruthenium Nitrosyl Moiety in Clusters: Trinuclear Linear μ-Hydroxido Magnesium(II)-Diruthenium(II), μ-Oxido Trinuclear Diiron(III)-Ruthenium(II), and Tetranuclear μ-Oxido Trigallium(III)-Ruthenium(II) Complexes.钌亚硝酰基簇合物中的钌：三核线性 μ-羟基金属镁(II)-二钌(II)、μ-氧代三核二铁(III)-钌(II)和四核 μ-氧代三镓(III)-钌(II)配合物。
Inorg Chem. 2022 Jan 17;61(2):950-967. doi: 10.1021/acs.inorgchem.1c03011. Epub 2021 Dec 28.

本文引用的文献

1
Unique Single-Atom Binding of Pseudohalogeno Ligands to Four Metal Ions Induced by Their Trapping into High-Nuclearity Cages.拟卤代配体通过被困入高核笼中而与四种金属离子形成的独特单原子键合。
Angew Chem Int Ed Engl. 2001 Mar 2;40(5):884-886. doi: 10.1002/1521-3773(20010302)40:5<884::AID-ANIE884>3.0.CO;2-C.
2
Magnetostructural correlations in polynuclear complexes: the Fe4 butterflies.
J Am Chem Soc. 2006 Dec 13;128(49):15722-7. doi: 10.1021/ja0641498.
3
Microwave-assisted synthesis of a hexanuclear Mn(III) single-molecule magnet.微波辅助合成六核锰（III）单分子磁体。
Inorg Chem. 2006 Jul 10;45(14):5272-4. doi: 10.1021/ic0606678.
4
An iron(III) phosphonate cluster containing a nonanuclear ring.
Chem Commun (Camb). 2006 Apr 28(16):1745-7. doi: 10.1039/b600763e. Epub 2006 Mar 13.
5
Hexanuclear iron(III) salicylaldoximato complexes presenting the [Fe6(mu3-O)2(mu2-OR)2]12+ core: syntheses, crystal structures, and spectroscopic and magnetic characterization.具有[Fe6(μ3-O)2(μ2-OR)2]12+核心的六核铁(III)水杨醛肟配合物：合成、晶体结构以及光谱和磁性表征
Inorg Chem. 2006 Mar 6;45(5):2317-26. doi: 10.1021/ic051945q.
6
An octanuclear complex containing the [Fe3O]7+ metal core: structural, magnetic, Mössbauer, and electron paramagnetic resonance studies.一种含有[Fe3O]7+金属核心的八核配合物：结构、磁性、穆斯堡尔谱和电子顺磁共振研究。
Inorg Chem. 2006 Jan 9;45(1):443-53. doi: 10.1021/ic051652x.
7
Proton NMR spectroscopy and magnetic properties of a solution-stable dicopper(II) complex bearing a single mu-hydroxo bridge.具有单个μ-羟基桥的溶液稳定二铜（II）配合物的质子核磁共振光谱和磁性
Inorg Chem. 2005 Jun 13;44(12):4372-82. doi: 10.1021/ic0501770.
8
Initial observation of magnetization hysteresis and quantum tunneling in mixed manganese-lanthanide single-molecule magnets.混合锰-镧系单分子磁体中磁化滞后和量子隧穿的初步观察。
J Am Chem Soc. 2004 Dec 8;126(48):15648-9. doi: 10.1021/ja0452727.
9
Spectroscopic demonstration of a large antisymmetric exchange contribution to the spin-frustrated ground state of a D3 symmetric hydroxy-bridged trinuclear Cu(II) complex: ground-to-excited state superexchange pathways.光谱学证明了在具有D3对称性的羟基桥连三核Cu(II)配合物的自旋受挫基态中，存在很大的反对称交换贡献：基态到激发态的超交换途径。
J Am Chem Soc. 2004 Oct 6;126(39):12586-95. doi: 10.1021/ja046380w.
10
Antisymmetric exchange in two tricopper(II) complexes containing a [Cu3(micro3-OMe)]5+ core.
Dalton Trans. 2004 Jan 7(1):59-64. doi: 10.1039/b311980g. Epub 2003 Nov 14.