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基于轴向不对称1,1'-联萘和电致变色紫精的电驱动手性光学开关：合成与光学性质

Electrically-driven chiroptical switches based on axially dissymmetric 1,1'-binaphthyl and electrochromic viologens: synthesis and optical properties.

作者信息

Deng Jian, Song Naiheng, Zhou Qifeng, Su Zhixing

机构信息

College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, Gansu 730000, China.

出版信息

Org Lett. 2007 Dec 20;9(26):5393-6. doi: 10.1021/ol701822u. Epub 2007 Nov 30.

DOI:10.1021/ol701822u
PMID:18047352
Abstract

A novel redox type of chiral molecular switch based on axially dissymmetric 1,1'-binaphthyl and electrochromic 4,4'-bipyridinium exhibits drastic changes in absorption and circular dichroism spectra upon electrochemical redox reaction and is fully characterized for the electrically driven chiroptical switching properties.

摘要

一种基于轴向不对称1,1'-联萘和电致变色4,4'-联吡啶鎓的新型氧化还原型手性分子开关，在电化学氧化还原反应时吸收光谱和圆二色光谱会发生剧烈变化，并且对其电驱动的手性光开关特性进行了全面表征。

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