氯二氟甲基苯砜：一种新型的基于非消耗臭氧层物质的二氟卡宾试剂，用于O-和N-二氟甲基化反应。
Chlorodifluoromethyl phenyl sulfone: a novel non-ozone-depleting substance-based difluorocarbene reagent for O- and N-difluoromethylations.
作者信息
Zheng Ji, Li Ya, Zhang Laijun, Hu Jinbo, Meuzelaar Gerrit Joost, Federsel Hans-Jürgen
机构信息
Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, China.
出版信息
Chem Commun (Camb). 2007 Dec 28(48):5149-51. doi: 10.1039/b713156a. Epub 2007 Oct 16.
DOI:10.1039/b713156a
PMID:18060124
Abstract
Chlorodifluoromethyl phenyl sulfone, a previously unknown compound that can be readily prepared from non-ODS-based precursors, was found to act as a robust difluorocarbene reagent for O- and N-difluoromethylations.
摘要
氯二氟甲基苯砜是一种可由非消耗臭氧层物质前体轻松制备的前所未知的化合物，它被发现是一种用于O-和N-二氟甲基化反应的强大二氟卡宾试剂。
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