Steurer Walter, Deloudi Sofia
Laboratory of Crystallography, Department of Materials, ETH Zurich, Wolfgang-Pauli-Strasse 10, CH-8093 Zurich, Switzerland.
Acta Crystallogr A. 2008 Jan;64(Pt 1):1-11. doi: 10.1107/S0108767307038627. Epub 2007 Dec 21.
It took Dan Shechtman more than two years to get his discovery of an Al-Mn phase with icosahedral diffraction symmetry and sharp Bragg reflections published. A paradigm shift had to take place before this novel ordering state of matter - seemingly contradicting crystallographic laws - could be accepted. Today, more than 25 years later, the existence of quasicrystals is beyond doubt. However, not everything is settled yet. All the factors governing formation, growth, stability and structure of quasicrystals are still not fully understood, nor is it resolved whether their structures are strictly or only on average quasiperiodic, and it is still an open question why only quasicrystals with 5-, 8-, 10- and 12-fold rotational symmetry have been experimentally observed so far. These points will be addressed in this review article.
丹·谢赫特曼花了两年多时间才让他关于具有二十面体衍射对称性和清晰布拉格反射的铝锰相的发现得以发表。在这种看似与晶体学定律相矛盾的新型物质有序状态被接受之前,必须发生一场范式转变。如今,25 多年过去了,准晶体的存在已毋庸置疑。然而,并非所有问题都已解决。所有控制准晶体形成、生长、稳定性和结构的因素仍未被完全理解,其结构是严格准周期的还是仅平均为准周期的也尚未得到解决,而且为什么到目前为止仅通过实验观察到具有 5 重、8 重、10 重和 12 重旋转对称性的准晶体仍是一个悬而未决的问题。这些要点将在这篇综述文章中予以探讨。