Steurer Walter
Department of Materials, ETH Zurich, Leopold-Ruzicka-Weg 4, Zurich, 8093, Switzerland.
Acta Crystallogr A Found Adv. 2018 Jan 1;74(Pt 1):1-11. doi: 10.1107/S2053273317016540.
More than 35 years and 11 000 publications after the discovery of quasicrystals by Dan Shechtman, quite a bit is known about their occurrence, formation, stability, structures and physical properties. It has also been discovered that quasiperiodic self-assembly is not restricted to intermetallics, but can take place in systems on the meso- and macroscales. However, there are some blank areas, even in the centre of the big picture. For instance, it has still not been fully clarified whether quasicrystals are just entropy-stabilized high-temperature phases or whether they can be thermodynamically stable at 0 K as well. More studies are needed for developing a generally accepted model of quasicrystal growth. The state of the art of quasicrystal research is briefly reviewed and the main as-yet unanswered questions are addressed, as well as the experimental limitations to finding answers to them. The focus of this discussion is on quasicrystal structure analysis as well as on quasicrystal stability and growth mechanisms.
在丹·谢赫特曼发现准晶体35多年、发表了11000多篇相关论文之后,人们对准晶体的出现、形成、稳定性、结构和物理性质已经有了相当多的了解。人们还发现,准周期自组装并不局限于金属间化合物,在中观和宏观尺度的系统中也能发生。然而,即使在这个大框架的核心部分,仍存在一些空白领域。例如,准晶体究竟只是熵稳定的高温相,还是在0 K时也能热力学稳定,这一点仍未完全阐明。需要开展更多研究来建立一个被普遍接受的准晶体生长模型。本文简要回顾了准晶体研究的现状,探讨了尚未得到解答的主要问题以及寻找这些问题答案时存在的实验局限性。本次讨论的重点是准晶体结构分析以及准晶体稳定性和生长机制。