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A four-coordinate Fe(III) porphyrin cation.

作者信息

Fang Ming, Wilson Scott R, Suslick Kenneth S

机构信息

School of Chemical Sciences, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801, USA.

出版信息

J Am Chem Soc. 2008 Jan 30;130(4):1134-5. doi: 10.1021/ja078061l. Epub 2008 Jan 3.

DOI:10.1021/ja078061l
PMID:18171069
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2679638/
Abstract
摘要

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本文引用的文献

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Cytochromes c': biological models for the S = 3/2, 5/2 spin-state admixture?细胞色素c':S = 3/2、5/2自旋态混合的生物学模型?
Chem Rev. 2006 Jun;106(6):2550-79. doi: 10.1021/cr040416l.
2
Azide-inhibited bacterial heme oxygenases exhibit an S = 3/2 (dxz,dyz)3(dxy)1(dz2)1 spin state: mechanistic implications for heme oxidation.叠氮化物抑制的细菌血红素加氧酶呈现出S = 3/2 (dxz,dyz)3(dxy)1(dz2)1自旋态:对血红素氧化的机制启示。
J Am Chem Soc. 2005 Jul 13;127(27):9794-807. doi: 10.1021/ja0425987.
3
Pulsed EPR and NMR spectroscopy of paramagnetic iron porphyrinates and related iron macrocycles: how to understand patterns of spin delocalization and recognize macrocycle radicals.顺磁性卟啉铁及相关铁大环化合物的脉冲电子顺磁共振和核磁共振光谱:如何理解自旋离域模式并识别大环自由基。
Inorg Chem. 2003 Jul 28;42(15):4526-44. doi: 10.1021/ic026245p.
4
Electronic effects in transition metal porphyrins. 10. Effect of ortho substituents on the temperature dependence of the NMR spectra of a series of spin-admixed perchloratoiron(III) tetrakis(2,6- or 2,4,6-phenyl substituted)porphyrinates.过渡金属卟啉中的电子效应。10. 邻位取代基对一系列自旋混合的四(2,6 - 或2,4,6 - 苯基取代)卟啉高氯酸铁(III)核磁共振谱温度依赖性的影响。
Inorg Chem. 2000 Feb 7;39(3):532-40. doi: 10.1021/ic9907866.
5
The 5/2,3/2 Spin Admixture in the Chloroiron(III) Derivative of the Sterically Crowded 2,3,7,8,12,13,17,18-Octaethyl-5,10,15,20-tetraphenylporphyrin.
Angew Chem Int Ed Engl. 1999 Nov 2;38(21):3181-3183.
6
The spin 3/2 state and quantum spin mixtures in haem proteins.
Q Rev Biophys. 1976 May;9(2):181-215. doi: 10.1017/s0033583500002407.