Yang Yang, Zhao Yongnan, Yu Jianguo, Wu Shizhen, Wang Ruji
Institute of Nanostructured Materials, College of Materials Science and Chemical Engineering and Tianjin Key Laboratory of Fiber Modification and Functional Fiber, Tianjin Polytechnic University, Tianjin 300160, China.
Inorg Chem. 2008 Feb 4;47(3):769-71. doi: 10.1021/ic701825m. Epub 2008 Jan 5.
By using 1,3-cyclohexane-bis(methylamine) (CHBMA) as the template, a novel zinc phosphatophosphite (TJPU-3) with extra-large 20-ring channels was synthesized. Cobalt doping produced a bimetallic phosphite (TJPU-6) with 12-ring apertures. While the templates sit in the cis configuration in TJPU-3, they are in the trans configuration in TJPU-6. This result has the potential for separation and recognition of CHBMA isomers.
