光化学[2 + 2]环加成反应作为研究固态结构转变的一种工具。
Photochemical [2 + 2] cycloaddition as a tool to study a solid-state structural transformation.
作者信息
Nagarathinam Mangayarkarasi, Vittal Jagadese J
机构信息
Department of Chemistry, National University of Singapore, Singapore.
出版信息
Chem Commun (Camb). 2008 Jan 28(4):438-40. doi: 10.1039/b713586f. Epub 2007 Oct 29.
DOI:10.1039/b713586f
PMID:18188460
Abstract
The solid-state structural transformation of the hydrogen-bonded 1D coordination polymer Cd(bpe)(CH(3)COO)(2)(H(2)O), to a ladder-type structure is evident from a photochemical [2 + 2] cycloaddition reaction forming 100% rctt-cyclobutane isomer.
摘要
氢键连接的一维配位聚合物[Cd(bpe)(CH₃COO)₂(H₂O)]ₙ向阶梯型结构的固态结构转变，从形成100% rctt -环丁烷异构体的光化学[2 + 2]环加成反应中清晰可见。
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