• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

一维氢键两性离子铅（II）配合物的光二聚作用及其在溶液中的异构化。

Photodimerization of a 1D hydrogen-bonded zwitter-ionic lead(II) complex and its isomerization in solution.

作者信息

Peedikakkal Abdul Malik Puthan, Koh Lip L, Vittal Jagadese J

机构信息

Department of Chemistry, National University of Singapore, Singapore.

出版信息

Chem Commun (Camb). 2008 Jan 28(4):441-3. doi: 10.1039/b714355a. Epub 2007 Oct 29.

DOI:10.1039/b714355a
PMID:18188461
Abstract

A pair of bpe-H(+) ligands in a zwitter-ionic complex undergoes photochemical cycloaddition quantitatively accompanied by proton transfer and the cyclobutane ring isomerizes slowly in solution to two more isomers, catalyzed by CF(3)CO(2)H acid.

摘要

两性离子络合物中的一对bpe-H(+)配体发生光化学环加成反应，定量地伴随质子转移，并且在CF(3)CO(2)H酸的催化下，环丁烷环在溶液中缓慢异构化为另外两种异构体。

相似文献

1
Photodimerization of a 1D hydrogen-bonded zwitter-ionic lead(II) complex and its isomerization in solution.一维氢键两性离子铅（II）配合物的光二聚作用及其在溶液中的异构化。
Chem Commun (Camb). 2008 Jan 28(4):441-3. doi: 10.1039/b714355a. Epub 2007 Oct 29.
2
Solid-state photochemical [2+2] cycloaddition in a hydrogen-bonded metal complex containing several parallel and crisscross C=C bonds.含多个平行和交叉碳-碳双键的氢键金属配合物中的固态光化学[2+2]环加成反应
Chemistry. 2008;14(17):5329-34. doi: 10.1002/chem.200701494.
3
Role of anions in the synthesis of cyclobutane derivatives via [2 + 2] cycloaddition reaction in the solid state and their isomerization in solution.阴离子在固态下通过[2+2]环加成反应合成环丁烷衍生物及其在溶液中的异构化作用。
J Org Chem. 2011 Oct 7;76(19):7860-5. doi: 10.1021/jo201268p. Epub 2011 Aug 29.
4
Photochemical [2 + 2] cycloaddition as a tool to study a solid-state structural transformation.光化学[2 + 2]环加成反应作为研究固态结构转变的一种工具。
Chem Commun (Camb). 2008 Jan 28(4):438-40. doi: 10.1039/b713586f. Epub 2007 Oct 29.
5
Single-Crystal-to-Single-Crystal Transformation of Hydrogen-Bonded Triple-Stranded Ladder Coordination Polymer via Photodimerization Reaction.通过光二聚反应实现氢键连接的三链梯形配位聚合物的单晶到单晶转变
Inorg Chem. 2019 Aug 5;58(15):10167-10173. doi: 10.1021/acs.inorgchem.9b01276. Epub 2019 Jul 18.
6
Stacking of double bonds for photochemical [2+2] cycloaddition reactions in the solid state.固态下用于光化学[2+2]环加成反应的双键堆积。
Chem Commun (Camb). 2008 Nov 14(42):5277-88. doi: 10.1039/b809136f. Epub 2008 Sep 1.
7
Stereochemical nonrigidity of a chiral rhodium boryl hydride complex: a sigma-borane complex as transition state for isomerization.手性铑硼氢化物配合物的立体化学非刚性：一种σ-硼烷配合物作为异构化的过渡态。
J Am Chem Soc. 2008 Apr 2;130(13):4375-85. doi: 10.1021/ja077357o. Epub 2008 Mar 8.
8
Assembly of [(eta5-C5Me5)MoS3Cu3]-supported one-dimensional chains with single, double, triple, and quadruple strands.由[(η5-C5Me5)MoS3Cu3]支撑的单链、双链、三链和四链一维链的组装。
Inorg Chem. 2008 Jun 16;47(12):5332-46. doi: 10.1021/ic8003454. Epub 2008 May 17.
9
Self-assembly of electroactive thiacrown ruthenium(II) complexes into hydrogen-bonded chain and tape networks.电活性硫杂冠醚钌（II）配合物自组装成氢键链和带状网络。
Inorg Chem. 2008 Dec 15;47(24):11551-60. doi: 10.1021/ic8007359.
10
Solid-state NMR and X-ray analysis of structural transformations in O-H...N heterosynthons formed by hydrogen-bond-mediated molecular recognition.
J Org Chem. 2009 Mar 20;74(6):2261-70. doi: 10.1021/jo802673f.

引用本文的文献

1
Isomerism in double-pillared-layer coordination polymers - structures and photoreactivity.双柱层配位聚合物中的异构现象——结构与光反应活性
IUCrJ. 2018 Feb 14;5(Pt 2):182-189. doi: 10.1107/S2052252518001379. eCollection 2018 Mar 1.
2
In-situ X-ray diffraction snapshotting: determination of the kinetics of a photodimerization within a single crystal.原位X射线衍射快照：单晶内光二聚化动力学的测定
Sci Rep. 2014 Oct 29;4:6815. doi: 10.1038/srep06815.