一维氢键两性离子铅（II）配合物的光二聚作用及其在溶液中的异构化。
Photodimerization of a 1D hydrogen-bonded zwitter-ionic lead(II) complex and its isomerization in solution.
作者信息
Peedikakkal Abdul Malik Puthan, Koh Lip L, Vittal Jagadese J
机构信息
Department of Chemistry, National University of Singapore, Singapore.
出版信息
Chem Commun (Camb). 2008 Jan 28(4):441-3. doi: 10.1039/b714355a. Epub 2007 Oct 29.
DOI:10.1039/b714355a
PMID:18188461
Abstract
A pair of bpe-H(+) ligands in a zwitter-ionic complex undergoes photochemical cycloaddition quantitatively accompanied by proton transfer and the cyclobutane ring isomerizes slowly in solution to two more isomers, catalyzed by CF(3)CO(2)H acid.
摘要
两性离子络合物中的一对bpe-H(+)配体发生光化学环加成反应，定量地伴随质子转移，并且在CF(3)CO(2)H酸的催化下，环丁烷环在溶液中缓慢异构化为另外两种异构体。
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