通过光化学[2+2]环加成反应实现 1D 配位聚合物的单晶到单晶的转变。
Single-crystal to single-crystal transformation of 1D coordination polymer via photochemical [2+2] cycloaddition reaction.
机构信息
College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu, P R China.
出版信息
Dalton Trans. 2011 Mar 14;40(10):2170-2. doi: 10.1039/c0dt00931h. Epub 2010 Nov 9.
PMID:21060955
Abstract
Photochemical single-crystal to single-crystal transformation of one 1D polymer Cd(bpe)(CBA)(2) afforded a new 1D polymer Cd(rctt-tpcb)(0.5)(CBA)(2) which underwent hydrothermal reaction in strong acidic solution to form a 3D coordination polymer {[Cd(rtct-tpcb)Cl(2)]·2H(2)O}(n).
摘要
光化学单晶到单晶转化得到一个 1D 聚合物 Cd(bpe)(CBA)(2)，生成一个新的 1D 聚合物 Cd(rctt-tpcb)(0.5)(CBA)(2)，该聚合物在强酸溶液中进行水热反应形成一个 3D 配位聚合物 {[Cd(rtct-tpcb)Cl(2)]·2H(2)O}(n)。
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