在钌催化的乙酸单取代烯丙酯与丙二酸根阴离子的烯丙基烷基化反应中区域化学的保留。
Retention of regiochemistry of monosubstituted allyl acetates in the ruthenium catalysed allylic alkylation with malonate anion.
作者信息
Kawatsura Motoi, Ata Fumio, Hayase Shuichi, Itoh Toshiyuki
机构信息
Department of Materials Science, Faculty of Engineering, Tottori University, Koyama, Tottori, 680-8552, Japan.
出版信息
Chem Commun (Camb). 2007 Nov 7(41):4283-5. doi: 10.1039/b709218k.
DOI:10.1039/b709218k
PMID:18217606
Abstract
In the RuCl2(p-cymene)/PPh3 catalysed regioselective allylic alkylation of monosubstituted allyl acetates with malonate anion, the selective substitution at the position originally substituted with acetate was observed.
摘要
在RuCl2（对异丙基苯）/三苯基膦催化下，单取代烯丙基乙酸酯与丙二酸根阴离子发生区域选择性烯丙基烷基化反应时，观察到在最初被乙酸酯取代的位置发生了选择性取代。
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