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含铜（II）的晶体配合物反式-N,N'-双（水杨醛）-1',2'-环己二胺的光谱、热学和伏安研究

Spectroscopic, thermal and voltammetric studies of crystalline complex trans-N,N'-bis(salicylidene)-1',2'-cyclohexanediamine with Cu(II).

作者信息

Aslantas Mehmet, Tümer Mehmet, Sahin Ertan

机构信息

Department of Physics, Kahramanmaras Sutcuimam University, 46100 Kahramanmaras, Turkey.

出版信息

Spectrochim Acta A Mol Biomol Spectrosc. 2008 Nov 1;71(1):263-8. doi: 10.1016/j.saa.2007.12.015. Epub 2007 Dec 28.

DOI:10.1016/j.saa.2007.12.015
PMID:18249581
Abstract

The dimeric complex, [C20H20CuN2O2]2, has been prepared and characterized by thermal analysis, IR spectroscopy and single-crystal X-ray diffraction techniques. The Cu atom in the binuclear complex exists in a distorted square-pyramidal configuration, defined by three O atoms and two N atoms. The crystal structure is stabilized by intermolecular C-H...O hydrogen bonding interaction. The electrochemical property of the complex was investigated in CH2Cl2 by cyclic voltammetry at 100 mV s(-1) scan rate.

摘要

已制备出二聚体配合物[C20H20CuN2O2]2，并通过热分析、红外光谱和单晶X射线衍射技术对其进行了表征。双核配合物中的铜原子以扭曲的四方锥构型存在，由三个氧原子和两个氮原子界定。晶体结构通过分子间C-H...O氢键相互作用得以稳定。在二氯甲烷中，以100 mV s(-1)的扫描速率通过循环伏安法研究了该配合物的电化学性质。

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