钯催化炔烃与亚膦酸酯的脱氢顺式双磷酸化反应生成(Z)-双磷酰基-1-烯烃。
Palladium-catalyzed dehydrogenative cis double phosphorylation of alkynes with H-phosphonate leading to (Z)-bisphosphoryl-1-alkenes.
作者信息
Han Li-Biao, Ono Yutaka, Shimada Shigeru
机构信息
National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki, Japan.
出版信息
J Am Chem Soc. 2008 Mar 5;130(9):2752-3. doi: 10.1021/ja7108272. Epub 2008 Feb 8.
PMID:18257571
Abstract
Dehydrogenative cis double phosphorylation of terminal alkynes with H-phosphonate took place efficiently in the presence of a divalent palladium catalyst to afford (Z)-bisphosphoryl-1-alkenes selectively.
摘要
在二价钯催化剂存在下，末端炔烃与H-膦酸酯发生脱氢顺式双磷酸化反应，可高效、选择性地生成(Z)-双磷酰基-1-烯烃。
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