Ohmura Toshimichi, Oshima Kazuyuki, Suginome Michinori
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.
Chem Commun (Camb). 2008 Mar 28(12):1416-8. doi: 10.1039/b800181b. Epub 2008 Feb 18.
Palladium-catalysed cis- and trans-silaboration of terminal alkynes has been developed via the addition of (chlorodimethylsilyl)pinacolborane, followed by a one-pot conversion of the chloro group on the silicon atom to an isopropoxy group.
通过添加（氯二甲基甲硅烷基）频哪醇硼烷，然后将硅原子上的氯基团一锅法转化为异丙氧基，已开发出钯催化的末端炔烃的顺式和反式硅硼化反应。
