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[酞菁镍 - 二氧化钒薄膜相变的光谱特性研究]

[Study on spectral property of phase transition of PcNi-VO2 films].

作者信息

Yuan Hong-tao, Feng Ke-cheng, Zhang Xian-hui

机构信息

Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130033, China.

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2007 Oct;27(10):1933-5.

Abstract

Highly oriented VO2 thin films were deposited on sapphire substrate and [C8H17O]8 PcNi thin films were spin-coated onto VO2 thin films. The microstructure of VO2 thin films was studied with XRD. The phase transition was observed and the change in the optical properties of the PcNi/VO2 multilayer-films were investigated with infrared spectrometer. It was found that the mid-infrared transmittance of the complex films in the wavelength range 1.5 to 5.5 mm raised with PcNi coating. The thermochromism of PcNi/VO2 films did not changed compared with VO2 films and the transition temperature was the same as that of VO2. It can be anticipated that the optical limiting property of PcNi/VO2 films will be superior to that of VO2 thin films or PcNi thin films.

摘要

将高度取向的VO₂薄膜沉积在蓝宝石衬底上,并将[C₈H₁₇O]₈PcNi薄膜旋涂在VO₂薄膜上。用X射线衍射仪研究了VO₂薄膜的微观结构。观察到了相变,并用红外光谱仪研究了PcNi/VO₂多层膜光学性质的变化。发现复合薄膜在1.5至5.5毫米波长范围内的中红外透过率随着PcNi涂层的增加而提高。与VO₂薄膜相比,PcNi/VO₂薄膜的热致变色没有变化,转变温度与VO₂相同。可以预期,PcNi/VO₂薄膜的光限幅性能将优于VO₂薄膜或PcNi薄膜。

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