金属有机纳米胶囊的快速形成对自组装过程有了新的认识。
Rapid formation of metal-organic nano-capsules gives new insight into the self-assembly process.
作者信息
Dalgarno Scott J, Power Nicholas P, Warren John E, Atwood Jerry L
机构信息
Department of Chemistry, University of Missouri-Columbia, 601 S. College Avenue, Columbia, MO 65211, USA.
出版信息
Chem Commun (Camb). 2008 Apr 7(13):1539-41. doi: 10.1039/b719769a. Epub 2008 Feb 27.
Metal-organic pyrogallol[4]arene nano-capsules, mixed pyrogallol[4]arene nano-capsules, and mixed metal analogues have been rapidly synthesised by addition of excess copper nitrate to a methanol solution of the corresponding macrocycle(s) (or gallium nano-capsules for the mixed metal system); improved solubility allows for thorough study and elucidation of the assembly process for these discrete metal-organic assemblies.
通过向相应大环化合物的甲醇溶液（对于混合金属体系则为镓纳米胶囊）中加入过量硝酸铜，已快速合成了金属有机连苯三酚[4]芳烃纳米胶囊、混合连苯三酚[4]芳烃纳米胶囊以及混合金属类似物；溶解性的提高使得对这些离散的金属有机组装体的组装过程能够进行全面研究和阐释。
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