通过荧光光谱法探测四膦酸穴状配体配合物中完全可逆的客体交换
Fully reversible guest exchange in tetraphosphonate cavitand complexes probed by fluorescence spectroscopy.
作者信息
Biavardi Elisa, Battistini Gionata, Montalti Marco, Yebeutchou Roger M, Prodi Luca, Dalcanale Enrico
机构信息
Dipartimento di Chimica Organica e Industriale, Universita di Parma, and INSTM UdR Parma, Viale G. P. Usberti 17 A, I-43100 Parma, Italy.
出版信息
Chem Commun (Camb). 2008 Apr 14(14):1638-40. doi: 10.1039/b801729h. Epub 2008 Mar 5.
DOI:10.1039/b801729h
PMID:18368149
Abstract
We report here the monitoring of reversible guest inclusion in phosphonate cavitands through a large increase in luminescence intensity caused by the modulation of the exoergonicity of an electron-transfer reaction.
摘要
我们在此报告，通过电子转移反应的放能性调节引起的发光强度大幅增加，对膦酸酯穴状配体中可逆客体包合进行监测。
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