Lin Kae-Long, Wang Nian-Fu, Shie Je-Lueng, Lee Tzen-Chin, Lee Chau
Department of Environmental Engineering, National Ilan University, 1 Sec. 1, Shen Lung Road, I-Lan 260-41, Taiwan, ROC.
J Hazard Mater. 2008 Nov 30;159(2-3):471-5. doi: 10.1016/j.jhazmat.2008.02.044. Epub 2008 Mar 10.
This study discusses the thin film transistor liquid crystal display (TFT-LCD) waste glass-blended cement (WGBC) pastes. It presents their compressive strength, their products of hydration and solid silicates changes. The samples were subjected to Fourier transformation infrared spectroscopy, differential thermal and thermo-gravimetric analysis and (29)Si magnetic angle spinning/nuclear magnetic resonance. The experimental XRD results demonstrated the speciation of the TFT-LCD waste glass, and that the major component was SiO(2). At 40% substitution of TFT-LCD waste glass, at 28 days and 56 days, the compressive strength was 35% and 30% lower, respectively, than that of the Portland cement paste. The intensity of the Ca(OH)(2) band at 3,710 cm(-1) in the 56-day hydrated products of the WGBC pastes that contain TFT-LCD waste glass exhibit comparatively weak peaks suggesting that much Ca(OH)(2) during hydration was consumed. Later, the CSH contents of the WGBC pastes increased, revealing that liberated Ca(OH)(2) was consumed in pozzolanic reactions.
本研究探讨了薄膜晶体管液晶显示器(TFT-LCD)废玻璃掺合水泥(WGBC)浆体。介绍了它们的抗压强度、水化产物以及固体硅酸盐的变化。对样品进行了傅里叶变换红外光谱、差示热分析和热重分析以及(29)Si魔角旋转/核磁共振分析。实验XRD结果表明了TFT-LCD废玻璃的形态,其主要成分是SiO₂。在TFT-LCD废玻璃替代量为40%时,28天和56天时的抗压强度分别比波特兰水泥浆体低35%和30%。含有TFT-LCD废玻璃的WGBC浆体56天水化产物中3710 cm⁻¹处Ca(OH)₂谱带的强度显示出相对较弱的峰,这表明水化过程中有大量Ca(OH)₂被消耗。随后,WGBC浆体的CSH含量增加,这表明释放出的Ca(OH)₂在火山灰反应中被消耗。