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在瓷砖生产中使用薄膜晶体管液晶显示器(TFT-LCD)废玻璃。

Use of thin film transistor liquid crystal display (TFT-LCD) waste glass in the production of ceramic tiles.

作者信息

Lin Kae-Long

机构信息

Department of Environmental Engineering, National Ilan University, I-Lan 260, Taiwan, ROC.

出版信息

J Hazard Mater. 2007 Sep 5;148(1-2):91-7. doi: 10.1016/j.jhazmat.2007.02.004. Epub 2007 Feb 12.

Abstract

In this study, we employ the following operating conditions: varied pressure (25 kgf/cm(2)), sintering temperature (900-1200 degrees C), sintering time (6h), percentage of thin film transistor liquid crystal display (TFT-LCD) waste glass by weight (0-50%) and temperature rising at a rate of 5 degrees C/min, to fabricate clay tiles. The sintering characteristics of the clay blended with TFT-LCD waste glass tiles are examined to evaluate the feasibility of the reuse of TFT-LCD waste glass. TFT-LCD waste glass contains large amounts of glass. The TCLP leaching concentrations all met the ROC EPAs current regulatory thresholds. The addition of TFT-LCD waste glass to the mixture, increased the apparent weight loss. The incorporation of 50% TFT-LCD waste glass resulted in a significant increase in the porosity ratio of the specimens compared to the porosity ratio of the ceramic tile containing TFT-LCD waste glass. The main constituent in both the clay tile and the clay with TFT-LCD waste glass samples is quartz. Increasing the temperature resulted in an increase in the flexural strength and resistance to abrasion in the tiles. The porosity ratio decreases as shrinkage increases. The relation between the porosity ratio and the hardness of the tiles used in the study is also shown.

摘要

在本研究中,我们采用以下操作条件:变化的压力(25千克力/平方厘米)、烧结温度(900 - 1200摄氏度)、烧结时间(6小时)、薄膜晶体管液晶显示器(TFT - LCD)废玻璃的重量百分比(0 - 50%)以及以5摄氏度/分钟的速率升温,来制造粘土砖。研究了与TFT - LCD废玻璃混合的粘土的烧结特性,以评估TFT - LCD废玻璃再利用的可行性。TFT - LCD废玻璃含有大量玻璃。TCLP浸出浓度均符合中华民国环保署当前的监管阈值。向混合物中添加TFT - LCD废玻璃会增加表观失重。与含TFT - LCD废玻璃的瓷砖相比,掺入50%的TFT - LCD废玻璃会使试样的孔隙率显著增加。粘土砖和含TFT - LCD废玻璃的粘土样品中的主要成分都是石英。温度升高会导致瓷砖的抗弯强度和耐磨性增加。孔隙率随收缩率增加而降低。还展示了本研究中使用的瓷砖的孔隙率与硬度之间的关系。

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