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利用薄膜晶体管液晶显示器废玻璃作为火山灰质材料。

The utilization of thin film transistor liquid crystal display waste glass as a pozzolanic material.

作者信息

Lin K L, Huang Wu-Jang, Shie J L, Lee T C, Wang K S, Lee C H

机构信息

Department of Environmental Engineering, National Ilan University 1, Section 1, Shen Lung Road, Yi-Lan City 26047, Taiwan, ROC.

出版信息

J Hazard Mater. 2009 Apr 30;163(2-3):916-21. doi: 10.1016/j.jhazmat.2008.07.044. Epub 2008 Jul 17.

Abstract

This investigation elucidates the pozzolanic behavior of waste glass blended cement (WGBC) paste used in thin film transistor liquid crystal displays (TFT-LCD). X-ray diffraction (XRD) results demonstrate that the TFT-LCD waste glass was entirely non-crystalline. The leaching concentrations of the clay and TFT-LCD waste glass all met the current regulatory thresholds of the Taiwan EPA. The pozzolanic strength activity indices of TFT-LCD waste glass at 28 days and 56 days were 89% and 92%, respectively. Accordingly, this material can be regarded as a good pozzolanic material. The amount of TFT-LCD waste glass that is mixed into WGBC pastes affects the strength of the pastes. The strength of the paste clearly declined as the amount of TFT-LCD waste glass increased. XRD patterns indicated that the major difference was the presence of hydrates of calcium silicate (CSH, 2 theta=32.1 degrees), aluminate and aluminosilicate, which was present in WGBC pastes. Portland cement may have increased the alkalinity of the solution and induced the decomposition of the glass phase network. WGBC pastes that contained 40% TFT-LCD waste glass have markedly lower gel/space ratios and exhibit less degree of hydration than ordinary Portland cement (OPC) pastes. The most satisfactory characteristics of the strength were observed when the mixing ratio of the TFT-LCD waste glass was 10%.

摘要

本研究阐明了用于薄膜晶体管液晶显示器(TFT-LCD)的废玻璃掺合水泥(WGBC)浆体的火山灰活性。X射线衍射(XRD)结果表明,TFT-LCD废玻璃完全是非晶态的。粘土和TFT-LCD废玻璃的浸出浓度均符合台湾环保署目前的监管阈值。TFT-LCD废玻璃在28天和56天的火山灰强度活性指数分别为89%和92%。因此,这种材料可被视为一种良好的火山灰材料。混入WGBC浆体中的TFT-LCD废玻璃量会影响浆体的强度。随着TFT-LCD废玻璃量的增加,浆体强度明显下降。XRD图谱表明,主要差异在于WGBC浆体中存在硅酸钙水合物(CSH,2θ=32.1度)、铝酸盐和铝硅酸盐。波特兰水泥可能提高了溶液的碱度并诱导了玻璃相网络的分解。含有40%TFT-LCD废玻璃的WGBC浆体的凝胶/空间比明显较低,水化程度也低于普通波特兰水泥(OPC)浆体。当TFT-LCD废玻璃的混合比例为10%时,观察到最令人满意的强度特性。

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