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制革厂排水接收废水的评估及其对土壤和植物的影响,特别强调重金属的生物累积。

Assessment of drain water receiving effluent from tanneries and its impact on soil and plants with particular emphasis on bioaccumulation of heavy metals.

作者信息

Sahu R K, Katiyar S, Tiwari Jaya, Kisku G C

机构信息

Department of Environmental Sciences, C.S.J.M. University, Kanpur-208 024, India.

出版信息

J Environ Biol. 2007 Jul;28(3):685-90.

Abstract

In the present study, impact of tannery and other industrial effluents on the physico-chemical characteristics of loamy drain water and their consequent impact on soil and plants irrigated with effluent have been studied. The study reveals most of the parameter pH, BOD5 and COD at sampling station I was higher than station II. Waste water quality at both Stations I and II exceeded prescribed limits (BIS) for safe disposal of effluents into the surface water Samples of soil and vegetables from the land irrigated with loamy drain water has been collected and analyzed for Cu, Zn, Ni, Cr Pb and Cd. The different metals showed different enrichment factor for loamy drain water irrigated soil and are as follows: Cd 30% (max), Pb 26%, Zn 18%, Cr 5%, Cu 5%, Ni 2% (min). For plant samples collected at polluted sites are Ni 46% spinach (whole plant) (max), Zn 42% spinach (whole plant), Cr 39% spinach (whole plant), Cu 33% spinach (whole plant), Pb 20% potato tuber, Cd 20% potato tuber (min). The levels of Zn 145, Cu 5.25, and Ni 39.25 microg/ g in spinach, Pb 29.25, Cr 38. 25 and Cd 3.2 microg/g in potato tuber grown on polluted soil irrigated with contaminated drain water were found more than the reference value, which may create chronic health hazard problem to human and cattle through food chain in long run. Accumulation of toxic heavy metals may be build up in the agriculturally productive land where it is treated with contaminated effluent enrich with metals in turn bio-concentrated in the edible fodder/plants.

摘要

在本研究中,已对制革厂及其他工业废水对壤质排水的理化特性的影响以及这些废水随后对用其灌溉的土壤和植物的影响进行了研究。研究表明,采样站I的大多数参数pH、五日生化需氧量(BOD5)和化学需氧量(COD)高于采样站II。采样站I和II的废水水质均超过了将废水安全排放到地表水的规定限值(印度标准局)。已采集了用壤质排水灌溉的土地上的土壤和蔬菜样本,并对其中的铜、锌、镍、铬、铅和镉进行了分析。不同金属在壤质排水灌溉土壤中的富集系数不同,具体如下:镉30%(最高)、铅26%、锌18%、铬5%、铜5%、镍2%(最低)。在污染场地采集的植物样本中,镍在菠菜(全株)中含量为46%(最高)、锌在菠菜(全株)中含量为42%、铬在菠菜(全株)中含量为39%、铜在菠菜(全株)中含量为33%、铅在马铃薯块茎中含量为20%、镉在马铃薯块茎中含量为20%(最低)。在用受污染排水灌溉的污染土壤上生长的菠菜中锌含量为145微克/克、铜含量为5.25微克/克、镍含量为39.25微克/克,在马铃薯块茎中铅含量为29.25微克/克、铬含量为38.25微克/克、镉含量为3.2微克/克,这些含量均高于参考值,从长远来看,这可能通过食物链对人类和牲畜造成慢性健康危害问题。有毒重金属的积累可能会在农业生产用地上形成,在用富含金属的受污染废水处理后,这些金属会反过来在可食用饲料/植物中生物浓缩。

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