一种新型的钯催化烯烃氢烷氧基化反应，伴有双键迁移。

A novel palladium-catalyzed hydroalkoxylation of alkenes with a migration of double bond.

作者信息

Tan Jiajing, Zhang Zuhui, Wang Zhiyong

机构信息

Hefei National Laboratory for Physical Science at Microscale, Joint Laboratory of Green Synthetic Chemistry and Department of Chemistry, University of Science and Technology of China, Hefei 230026, PR China.

出版信息

Org Biomol Chem. 2008 Apr 21;6(8):1344-8. doi: 10.1039/b800838h. Epub 2008 Mar 17.

DOI:10.1039/b800838h

PMID:18385840

Abstract

A novel palladium-catalyzed addition of alcohols to olefins was developed, in which a migration of double bond was involved. By this new method, a variety of allylic ethers were prepared with moderate to high yields under mild conditions.

摘要

开发了一种新型钯催化的醇对烯烃的加成反应，该反应涉及双键迁移。通过这种新方法，在温和条件下以中等到高的产率制备了多种烯丙基醚。