一种新型功能化手性菲咯啉衍生物的合成、结构及金属络合行为
Synthesis, structure, and metal complexation behavior of a new type of functionalized chiral phenanthroline derivative.
作者信息
Plummer Jacob M, Weitgenant Jeremy A, Noll Bruce C, Lauher Joseph W, Wiest Olaf, Helquist Paul
机构信息
Department of Chemistry and Biochemistry and the Notre Dame Cancer Center, University of Notre Dame, Notre Dame, IN 46556, USA.
出版信息
J Org Chem. 2008 May 16;73(10):3911-4. doi: 10.1021/jo702566m. Epub 2008 Apr 10.
PMID:18399656
Abstract
SmI(2) serves as an effective promoter for the coupling of 1,10-phenanthroline with an epoxide to generate a new class of chiral, functionalized ligands that readily form complexes with metals. Structural studies of the resulting phenanthroline derivative and two of its metal complexes are reported.
摘要
二碘化钐（SmI₂）是将1,10 - 菲咯啉与环氧化物偶联以生成一类新型手性功能化配体的有效促进剂，这类配体能够轻易地与金属形成配合物。本文报道了所得菲咯啉衍生物及其两种金属配合物的结构研究。
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