Sbircea Lenuta, Sharma Narain D, Clegg William, Harrington Ross W, Horton Peter N, Hursthouse Michael B, Apperley David C, Boyd Derek R, James Stuart L
Centre for the Theory and Application of Catalysis, Queen's University Belfast, Belfast, Northern Ireland, UKBT9 5AG.
Chem Commun (Camb). 2008 Nov 21(43):5538-40. doi: 10.1039/b812366g. Epub 2008 Oct 9.
The first enantiopure 4,4'-bipyridyls, , , and have been prepared in four or five steps via bacterial dioxygenase-catalysed cis-dihydroxylation of 4-chloroquinoline and C-C coupling; ligands and are found to be effective building blocks for the preparation of chiral metal-organic frameworks as demonstrated with the rational synthesis of two pillared-grid structures [Zn(2)(fumarate)(2)(L)], which exhibit interesting structural and dynamic aspects.
首个对映体纯的4,4'-联吡啶，即 、 、 和 ，已通过细菌双加氧酶催化的4-氯喹啉顺式二羟基化反应和碳-碳偶联反应，经四步或五步制备而成；配体 和 被发现是制备手性金属有机骨架的有效构建单元，通过合理合成两种柱状网格结构[Zn(2)(富马酸盐)(2)(L)]得以证明，这两种结构展现出有趣的结构和动态特征。
