通过自组装配位笼的相互贯穿来构建芳香环堆叠结构。

Engineering stacks of aromatic rings by the interpenetration of self-assembled coordination cages.

作者信息

Yamauchi Yoshihiro, Yoshizawa Michito, Fujita Makoto

机构信息

Department of Applied Chemistry, School of Engineering, University of Tokyo, and PRESTO, Japan Science and Technology Agency, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.

出版信息

J Am Chem Soc. 2008 May 7;130(18):5832-3. doi: 10.1021/ja077783+. Epub 2008 Apr 15.

DOI:10.1021/ja077783+

PMID:18410107

Abstract

One-step quantitative self-assembly of aromatic towers consisting of seven to nine discretely stacked aromatic rings is achieved from 25-27 multicomponents via the interpenetration of two identical coordination cages.

摘要

由25至27种多组分通过两个相同配位笼的相互贯穿，实现了由七至九个离散堆叠的芳环组成的芳香塔的一步定量自组装。