Yoshida Masahiro, Komatsuzaki Yuki, Ihara Masataka
Graduate School of Pharmaceutical Sciences, The University of Tokushima, 1-78-1 Sho-machi, Tokushima, 770-8505, Japan.
Org Lett. 2008 May 15;10(10):2083-6. doi: 10.1021/ol800663v. Epub 2008 Apr 23.
A CO2-fixation reaction of 4-(benzylamino)-2-butynyl carbonates and benzoates, carried out in the presence of DBU, provides substituted 5-vinylideneoxazolidin-2-ones. The reaction has been successfully applied to the CO2-recycling process and fixation of atmospheric CO2.
在DBU存在下,4-(苄基氨基)-2-丁炔基碳酸酯和苯甲酸酯的二氧化碳固定反应可生成取代的5-亚乙烯基恶唑烷-2-酮。该反应已成功应用于二氧化碳循环过程和大气二氧化碳的固定。