Sunarso Jaka, Ismadji Suryadi
Department of Chemical Engineering, Widya Mandala Surabaya Catholic University, Kalijudan 37, Surabaya 60114, Indonesia.
J Hazard Mater. 2009 Jan 15;161(1):1-20. doi: 10.1016/j.jhazmat.2008.03.069. Epub 2008 Mar 21.
Supercritical fluid has been adopted as an extraction media to remove various kinds of substances from distinct types of solid matrices since three decades ago. Compared to conventional extraction mode, supercritical fluid extraction technology is preferred because of the flexibility in adjusting its dissolving power and inherent elimination of organic solvent which means reducing time and money needed for subsequent purification. Utilization of this method as an environmental remedial technology, however, has become a trend only after its accomplishment in analytical chemistry was acknowledged. This review tries to summarize in a comprehensive manner the multitude aspects involved in hazardous compounds removal from miscellaneous class of environmental matrices. The industrial adsorbent regeneration using supercritical fluid technology is also discussed. Although, this technology has been successfully realized for environmental remediation in laboratory and on pilot-plant scale, its commercialization attempts still lack significant technology improvement in order to reach the economic feasibility.
自三十年前起,超临界流体就已被用作萃取介质,用于从不同类型的固体基质中去除各种物质。与传统萃取方式相比,超临界流体萃取技术更受青睐,因为它在调节溶解能力方面具有灵活性,且无需使用有机溶剂,这意味着减少了后续纯化所需的时间和成本。然而,直到其在分析化学领域的应用取得成功后,将该方法用作环境修复技术才成为一种趋势。本综述试图全面总结从各类环境基质中去除有害化合物所涉及的诸多方面。还讨论了使用超临界流体技术进行工业吸附剂再生的情况。尽管该技术已在实验室和中试规模上成功用于环境修复,但其商业化尝试仍缺乏重大技术改进,以实现经济可行性。