Qiao Wei, Wang Wei, Li Pan, Xun Rui
Department of Environmental Science and Engineering, Tsinghua University, Beijing 100084, China.
Huan Jing Ke Xue. 2008 Jan;29(1):152-7.
Sewage sludge thermal hydrolysis experiments with 2,450 MHz microwave energy were carried out under 80-170 degrees C with 1-30 min. Max. microwave output power was 1 kW. Volatile suspended solid (VSS) dissolving ratio, COD dissolving ratio, liquor COD and TOC, sludge particle size distribution, micro-structure, and elements (C, H and N) hydrolysis were measured. Also, sludge dewaterability improvement was inspected. Results show that microwave heating leads fast sludge hydrolysis reaction. Temperature was the controlling process factor. Under 150 degrees C and 170 degrees C with 5 min, 15.8% and 29.4% VSS dissolved respectively. While, with 10 min 19.07% and 25.75% COD moved to liquor. Release of organic materials increased liquid sludge COD and TOC concentration. Under 170 degrees C with 10 min, COD and TOC concentration were 9,860.0 mg/L and 2,949.70 mg/L respectively. More than 5 to 10 min, VSS and COD dissolving trend turned slow down. SEM test showed cell disruption of hydrolyzed sludge. N could dissolve more easily than C and H. 67% N hydrolysiszed under 170 degrees C with 5 min. Bacterial cell disruption and organic solid hydrolysis improved sludge dewaterability. Sludge cake moisture content decreased from 82% to 73.1% and 65.5% under 150 degrees C, 170 degrees C with 10 min microwave hydrolysis. Accordingly, sludge amount reduction ratios were 33.9% and 51.7% respectively.
利用2450兆赫微波能量进行了污水污泥热水解实验,实验温度为80至170摄氏度,时长为1至30分钟。最大微波输出功率为1千瓦。测量了挥发性悬浮固体(VSS)溶解率、化学需氧量(COD)溶解率、液体COD和总有机碳(TOC)、污泥粒径分布、微观结构以及元素(碳、氢和氮)的水解情况。此外,还考察了污泥脱水性能的改善情况。结果表明,微波加热能使污泥水解反应快速进行。温度是控制过程的因素。在150摄氏度和170摄氏度下反应5分钟时,VSS溶解率分别为15.8%和29.4%。而反应10分钟时,19.07%和25.75%的COD转移至液相中。有机物质的释放增加了液体污泥的COD和TOC浓度。在170摄氏度下反应10分钟时,COD和TOC浓度分别为9860.0毫克/升和2949.70毫克/升。超过5至10分钟后,VSS和COD的溶解趋势减缓。扫描电子显微镜(SEM)测试显示水解污泥的细胞破裂。氮比碳和氢更容易溶解。在170摄氏度下反应5分钟时,67%的氮发生了水解。细菌细胞破裂和有机固体水解改善了污泥的脱水性能。在150摄氏度、170摄氏度下进行10分钟微波水解后,污泥饼的含水量分别从82%降至73.1%和65.5%。相应地,污泥减量率分别为33.9%和51.7%。