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流体界面处的椭球形颗粒。

Ellipsoidal particles at fluid interfaces.

作者信息

Lehle H, Noruzifar E, Oettel M

机构信息

Max-Planck-Institut für Metallforschung, Heisenbergstr. 3, Stuttgart, Germany.

出版信息

Eur Phys J E Soft Matter. 2008 May-Jun;26(1-2):151-60. doi: 10.1140/epje/i2007-10314-1. Epub 2008 May 2.

Abstract

For partially wetting, ellipsoidal colloids trapped at a fluid interface, their effective, interface-mediated interactions of capillary and fluctuation-induced type are analyzed. For contact angles different from 90( degrees ) , static interface deformations arise which lead to anisotropic capillary forces that are substantial already for micrometer-sized particles. The capillary problem is solved using an efficient perturbative treatment which allows a fast determination of the capillary interaction for all distances between and orientations of two particles. Besides static capillary forces, fluctuation-induced forces caused by thermally excited capillary waves arise at fluid interfaces. For the specific choice of a spatially fixed three-phase contact line, the asymptotic behavior of the fluctuation-induced force is determined analytically for both the close-distance and the long-distance regime and compared to numerical solutions.

摘要

对于部分润湿且被困在流体界面处的椭球形胶体,分析了它们由毛细作用和涨落诱导类型的有效界面介导相互作用。对于接触角不同于90度的情况,会出现静态界面变形,这会导致各向异性的毛细力,对于微米级颗粒而言,这种力已经相当可观。使用一种有效的微扰处理方法解决了毛细问题,该方法能够快速确定两个颗粒之间所有距离和取向的毛细相互作用。除了静态毛细力外,流体界面处还会出现由热激发毛细波引起的涨落诱导力。对于空间固定的三相接触线的特定选择,解析确定了涨落诱导力在近距离和远距离区域的渐近行为,并与数值解进行了比较。

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