Morris Russell E, Wheatley Paul S
EaStChem School of Chemistry, University of St Andrews, Purdie Building, St Andrews KY16 9ST, UK.
Angew Chem Int Ed Engl. 2008;47(27):4966-81. doi: 10.1002/anie.200703934.
Gas storage in solids is becoming an ever more important technology, with applications and potential applications ranging from energy and the environment all the way to biology and medicine. Very highly porous materials, such as zeolites, carbon materials, polymers, and metal-organic frameworks, offer a wide variety of chemical composition and structural architectures that are suitable for the adsorption and storage of many different gases, including hydrogen, methane, nitric oxide, and carbon dioxide. However, the challenges associated with designing materials to have sufficient adsorption capacity, controllable delivery rates, suitable lifetimes, and recharging characteristics are not trivial in many instances. The different chemistry associated with the various gases of interest makes it necessary to carefully match the properties of the porous material to the required application.
固体中的气体存储正成为一项日益重要的技术,其应用和潜在应用涵盖能源、环境乃至生物学和医学等各个领域。诸如沸石、碳材料、聚合物和金属有机框架等具有超高孔隙率的材料,提供了多种多样的化学成分和结构架构,适用于吸附和存储许多不同的气体,包括氢气、甲烷、一氧化氮和二氧化碳。然而,在许多情况下,设计具有足够吸附容量、可控释放速率、合适使用寿命和再充电特性的材料所面临的挑战并非微不足道。与各种目标气体相关的不同化学性质使得有必要仔细将多孔材料的特性与所需应用相匹配。