铜催化二硼试剂对α,β-炔酸酯的加成反应：β-硼基-α,β-烯酸酯的高效合成
Copper-catalyzed addition of diboron reagents to alpha,beta-acetylenic esters: efficient synthesis of beta-boryl-alpha,beta-ethylenic esters.
作者信息
Lee Ji-Eon, Kwon Jisook, Yun Jaesook
机构信息
Department of Chemistry and Institute of Basic Science, Sungkyunkwan University, Suwon 440-746, Korea.
出版信息
Chem Commun (Camb). 2008 Feb 14(6):733-4. doi: 10.1039/b716697d.
DOI:10.1039/b716697d
PMID:18478706
Abstract
The efficient copper-catalyzed addition reaction of bis(pinacolato)diboron to alpha,beta-acetylenic esters has been developed, which produces the corresponding beta-borylated-alpha,beta-ethylenic esters in high yields under mild reaction conditions.
摘要
已开发出双（频哪醇合）二硼与α，β-炔酸酯的高效铜催化加成反应，该反应在温和的反应条件下能高产率地生成相应的β-硼化-α，β-烯酸酯。
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