Bedford Robin B, Betham Michael, Butts Craig P, Coles Simon J, Hursthouse Michael B, Noelle Scully P, Tucker James H R, Wilkie John, Willener Yasmine
School of Chemistry, University of Bristol, Cantock's Close, Bristol, UKBS8 1TS.
Chem Commun (Camb). 2008 Jun 7(21):2429-31. doi: 10.1039/b801823e. Epub 2008 Apr 23.
A novel organometallic receptor binds anions in solution and in the solid state, with complexes stabilised through a series of C-HX interactions, as evidenced by 1H NMR spectroscopy, X-ray crystallography and computational models.
一种新型有机金属受体在溶液和固态中均能结合阴离子,其配合物通过一系列C-HX相互作用得以稳定,这一点通过¹H NMR光谱、X射线晶体学和计算模型得到了证实。