一种简洁的首次合成具有两个手性原子的α-氨基次膦酸酯的方法，可得到光学纯的α-氨基-H-次膦酸。 - Suppr

A concise and first synthesis of alpha-aminophosphinates with two stereogenic atoms leading to optically pure alpha-amino-H-phosphinic acids.

作者信息

Zhang Dehui, Yuan Chengye

机构信息

State Key Laboratory of Bio-organic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Feng-lin Rd., Shanghai, 200032, China.

出版信息

Chemistry. 2008;14(20):6049-52. doi: 10.1002/chem.200800690.

DOI:10.1002/chem.200800690

PMID:18491337

Abstract

摘要

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A concise and first synthesis of alpha-aminophosphinates with two stereogenic atoms leading to optically pure alpha-amino-H-phosphinic acids.

作者信息

Zhang Dehui, Yuan Chengye

机构信息

State Key Laboratory of Bio-organic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Feng-lin Rd., Shanghai, 200032, China.