磷酸化甲醛衍生物的化学。第一部分。
Chemistry of phosphorylated formaldehyde derivatives. Part I.
作者信息
Morgalyuk Vasily P
机构信息
Laboratory of Organophosphorus Compounds, Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova str., 28, Moscow 119991, Russia.
出版信息
Molecules. 2014 Aug 25;19(9):12949-3009. doi: 10.3390/molecules190912949.
The underinvestigated derivatives of unstable phosphorylated formaldehyde acetals and some of the structurally related compounds, such as thioacetals, aminonitriles, aminomethylphosphinoyl compounds, are considered. Separately considered are halogen aminals of phosphorylated formaldehyde, acetals of phosphorylated formaldehyde of H-phosphinate-type and a phosphorylated gem-diol of formaldehyde. Synthetic methods, chemical properties and examples of practical applications are given.
本文考虑了研究较少的不稳定磷酸化甲醛缩醛衍生物以及一些结构相关的化合物，如硫缩醛、氨基腈、氨基甲基膦酰化合物。另外还分别考虑了磷酸化甲醛的卤代缩醛、次膦酸酯型磷酸化甲醛的缩醛以及磷酸化甲醛偕二醇。文中给出了合成方法、化学性质及实际应用示例。
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