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用于微波/毫米波介质的堇青石烧结条件。

Sintering conditions of cordierite for microwave/millimeterwave dielectrics.

作者信息

Ohsato Hitoshi, Terada Mio, Kagomiya Isao, Kawamura Keizou, Kakimoto Ken-Ichi, Kim Eung Soo

机构信息

Materials Science and Engineering, Shikumi-College, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan.

出版信息

IEEE Trans Ultrason Ferroelectr Freq Control. 2008 May;55(5):1081-5. doi: 10.1109/TUFFC.2008.760.

Abstract

With the advent of ubiquitous age, the high-quality, dielectric materials have been required for the applications of wireless communications available to millimeterwave as well as microwave frequencies such as ultra-high speed local area network (LAN), electronic toll collection (ETS), and car anticollision systems on the intelligent transport system (ITS), and so on. Cordierite (Mg(2)Al(4)Si(5)O(18)), which is one of the silicates, is a good candidate for microwave/ millimeterwave dielectrics due to low dielectric constant epsilon(r) and low loss. This study is focused on optimization of the sintering condition of cordierite. A single phase of cordierite could be obtained from the powders calcined from 1355 degrees C to 1375 degrees C for 3 hours, and the samples sintered from 1375 degrees C to 1440 degrees C for 2 hours. The highest relative density of 98.7% was obtained for the samples sintered at 1440 degrees C for 2 hours. The dielectric constant and the quality factor of cordierite depend on the sintering temperatures. The density also was improved to 2.51 g/cm(3) by a slower heating and cooling rate of 3 degrees C/minute. The microwave dielectric properties are as follows: epsilon(r) = 6.14, Q . f = 59682 GHz, and tau(f) = -26.1 ppm/ degrees C.

摘要

随着泛在时代的到来,对于毫米波以及微波频率的无线通信应用,如超高速局域网(LAN)、电子不停车收费系统(ETS)以及智能交通系统(ITS)中的汽车防撞系统等,都需要高质量的介电材料。堇青石(Mg₂Al₄Si₅O₁₈)作为硅酸盐的一种,因其低介电常数εᵣ和低损耗,是微波/毫米波介质的良好候选材料。本研究聚焦于堇青石烧结条件的优化。从1355℃至1375℃煅烧3小时的粉末以及从1375℃至1440℃烧结2小时可获得单相堇青石。在1440℃烧结2小时的样品获得了98.7%的最高相对密度。堇青石的介电常数和品质因数取决于烧结温度。通过3℃/分钟的较慢加热和冷却速率,密度也提高到了2.51g/cm³。微波介电性能如下:εᵣ = 6.14,Q·f = 59682GHz,τ(f) = -26.1ppm/℃。

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