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公路旁土壤中重金属的横向输入模式及浸出性

Transversal immission patterns and leachability of heavy metals in road side soils.

作者信息

Hjortenkrans David S T, Bergbäck Bo G, Häggerud Agneta V

机构信息

School of Pure and Applied Natural Sciences, University of Kalmar, Sweden.

出版信息

J Environ Monit. 2008 Jun;10(6):739-46. doi: 10.1039/b804634d. Epub 2008 May 15.

Abstract

Today there is consensus concerning the road traffic's role as a metal source. However, there are so far only a few studies which focus on the road side immission patterns regarding distance from roads, and especially in combination with the leachability of heavy metals down the soil profile. In this study, the aim was to analyse concentrations of traffic related metals in road side soils, at different depths and distances from roads, both to analyse the immission patterns as well as to explain the importance of the road construction design of the road side terrain. The BCR sequential extraction procedure was performed to be able to address the environmental risk in terms of metal mobility. Approximately 80 soil samples were analysed for seven metals; antimony (Sb), cadmium (Cd), copper (Cu), chromium (Cr), lead (Pb), nickel (Ni) and zinc (Zn). The results showed that, depending on metal, the total metal concentrations in road side soils have increased 3-16 times compared to regional background during the last decades. Each metal had a limited dispersal distance from the roads as well as down in the soil profile and the road construction significantly affected the metal immission distance. Elevated metal concentrations were mostly found for top soils and down to 10 cm in the soil profiles. The labile fractions counted for more than 40% of the total concentrations for Cd, Cu, Ni, Pb and Zn, indicating a potential mobilization of the metals if the road side soils become disturbed. The present soil metal concentration levels are not alarming, but metals with a high accumulation rate might gradually be an upcoming problem if nothing is done to their emission sources.

摘要

如今,人们对于道路交通作为金属来源的作用已达成共识。然而,迄今为止,仅有少数研究关注道路旁污染物排放模式与距道路距离的关系,尤其是与重金属在土壤剖面中的淋溶性相结合的情况。在本研究中,目的是分析道路旁不同深度和距道路不同距离处土壤中与交通相关的金属浓度,以分析污染物排放模式,并解释道路旁地形的道路建设设计的重要性。采用BCR连续提取程序以便从金属迁移性方面评估环境风险。对约80个土壤样本中的七种金属进行了分析,包括锑(Sb)、镉(Cd)、铜(Cu)、铬(Cr)、铅(Pb)、镍(Ni)和锌(Zn)。结果表明,在过去几十年中,根据金属种类不同,道路旁土壤中的总金属浓度相较于区域背景值增加了3至16倍。每种金属在距道路以及土壤剖面中的扩散距离都有限,道路建设对金属污染物排放距离有显著影响。金属浓度升高主要出现在表层土壤以及土壤剖面中至10厘米深度处。对于镉、铜、镍、铅和锌,不稳定部分占总浓度的40%以上,这表明如果道路旁土壤受到扰动,这些金属可能会发生迁移。目前土壤中的金属浓度水平并不令人担忧,但如果不对其排放源采取措施,具有高积累率的金属可能会逐渐成为一个新问题。

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