Tranchemontagne David J, Ni Zheng, O'Keeffe Michael, Yaghi Omar M
Center for Reticular Chemistry, Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095, USA.
Angew Chem Int Ed Engl. 2008;47(28):5136-47. doi: 10.1002/anie.200705008.
Metal-organic polyhedra (MOPs), are discrete metal-organic molecular assemblies. They are useful as host molecules that can provide tailorable internal volume in terms of metrics, functionality, and active metal sites. As a result, these materials are potentially useful for a variety of applications, such as highly selective guest inclusion and gas storage, and as nanoscale reaction vessels. This review identifies the nine most important polyhedra, and describes the design principles for the five polyhedra most likely to result from the assembly of secondary building units, and provides examples of these shapes that are known as metal-organic crystals.
金属有机多面体（MOPs）是离散的金属有机分子聚集体。它们作为主体分子很有用，能够在尺寸、功能和活性金属位点方面提供可定制的内部空间。因此，这些材料在多种应用中具有潜在用途，例如高选择性客体包合和气体存储，以及作为纳米级反应容器。本综述确定了九种最重要的多面体，并描述了最有可能由二级构建单元组装而成的五种多面体的设计原则，还提供了这些被称为金属有机晶体的形状的示例。
