分子多面体与金属有机框架之间的相互转化。
Interconversion between molecular polyhedra and metal-organic frameworks.
作者信息
Li Jian-Rong, Timmons Daren J, Zhou Hong-Cai
机构信息
Department of Chemistry, Texas A&M University, P.O. Box 30012, College Station, Texas 77842-3012, USA.
出版信息
J Am Chem Soc. 2009 May 13;131(18):6368-9. doi: 10.1021/ja901731z.
PMID:19374418
Abstract
The construction of a metal-organic framework (MOF) with a pcu-a topology using a preassembled soluble molecular octahedron has been realized experimentally. The resulting MOF can also be reversibly converted to the molecular octahedron. All such conversions are based on axial-ligand substitution reactions on the molecular octahedron.
摘要
利用预组装的可溶性分子八面体通过实验实现了具有pcu-a拓扑结构的金属有机框架（MOF）的构建。所得的MOF也可以可逆地转化为分子八面体。所有这些转化都基于分子八面体上的轴向配体取代反应。
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