Bove Livia E, Petrillo C, Fontana A, Sokolov A P
INFM CRS-SOFT, c/o Universita' di Roma La Sapienza, Rome, Italy.
J Chem Phys. 2008 May 14;128(18):184502. doi: 10.1063/1.2912060.
By applying a new two-step line-shape analysis to inelastic neutron and x-ray scattering spectra of glassy systems, we were able to resolve the acoustic excitations from the low-frequency excess modes and to accurately estimate the damping of sound waves in the terahertz frequency range. Using this approach, we estimated the damping parameter for terahertz acoustic waves in a wide class of chemically different glasses and did a quantitative comparison of the results with prediction of theoretical models. By comparing the estimates of the mean-free path of the acoustic modes in different glasses and the corresponding boson peak strengths, we show the existence of a simple correlation between these two quantities. The relationship between attenuation of the terahertz acoustic modes, strength of the boson peak, and fragility is discussed.
通过将一种新的两步线形分析方法应用于玻璃态系统的非弹性中子散射光谱和X射线散射光谱,我们能够分辨出低频过剩模式中的声学激发,并准确估计太赫兹频率范围内声波的阻尼。使用这种方法,我们估计了多种化学组成不同的玻璃中太赫兹声波的阻尼参数,并将结果与理论模型的预测进行了定量比较。通过比较不同玻璃中声学模式的平均自由程估计值和相应的玻色子峰强度,我们展示了这两个量之间存在简单的相关性。讨论了太赫兹声学模式的衰减、玻色子峰强度和脆性之间的关系。