2-（氨基芳基）烷酮O-苯基肟：用于喹唑啉合成的多功能试剂。
2-(Aminoaryl)alkanone O-phenyl oximes: versatile reagents for syntheses of quinazolines.
作者信息
Portela-Cubillo Fernando, Scott Jackie S, Walton John C
机构信息
University of St. Andrews, School of Chemistry, EaStChem, St. Andrews, Fife, UK KY16 9ST.
出版信息
Chem Commun (Camb). 2008 Jul 7(25):2935-7. doi: 10.1039/b803630f. Epub 2008 Apr 17.
DOI:10.1039/b803630f
PMID:18566730
Abstract
Microwave irradiations of 2-(aminoaryl)alkanone O-phenyl oximes and carbonyl compounds generate iminyl radicals in company with imines; iminyl on imine ring closure yields dihydroquinazolines or quinazolines when ZnCl2 is included in the mixture.
摘要
对2-（氨基芳基）烷酮O-苯基肟和羰基化合物进行微波辐照会伴随着亚胺生成亚胺基自由基；当混合物中含有氯化锌时，亚胺环上的亚胺基闭环会生成二氢喹唑啉或喹唑啉。
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