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野罂粟中的生物碱

Alkaloids from Papaver nudicaule L.

作者信息

Istatkova Ralitsa, Philipov Stefan, Yadamsurenghiin Gerelt-Od, Samdan Javzan, Dangaa Selenge

机构信息

Institute of Organic Chemistry with Centre of Phytochemistry, Bulgarian Academy of Sciences, Sofia, Bulgaria.

出版信息

Nat Prod Res. 2008 May 10;22(7):607-11. doi: 10.1080/14786410701605315.

Abstract

A new promorphinane alkaloid (-)-8,14-dihydroflavinantine was isolated from the aerial parts of Papaver nudicaule L. (Papaveraceae) growing in Mongolia. Six known isoquinoline alkaloids (+)-amuronine, pseudoprotopine, allocryptopine, (-)-dihydroamuronine, (-)-amurensinine N-oxide A and (-)-amurensinine N-oxide B were isolated, too. Pseudoprotopine has been found for the first time in a plant of the family Papaveraceae. (-)-dihydroamuronine, (-)-amurensinine N-oxide A and (-)-amurensinine N-oxide B are new for the genus Papaver. All structures were established using spectral and physical data.

摘要

从生长于蒙古的裸茎罂粟(罂粟科)地上部分分离得到一种新的原吗啡烷生物碱(-)-8,14-二氢黄酮宁。还分离得到六种已知的异喹啉生物碱(+)-阿穆罗宁、伪原托品、别隐品碱、(-)-二氢阿穆罗宁、(-)-阿穆尔任宁N-氧化物A和(-)-阿穆尔任宁N-氧化物B。伪原托品首次在罂粟科植物中被发现。(-)-二氢阿穆罗宁、(-)-阿穆尔任宁N-氧化物A和(-)-阿穆尔任宁N-氧化物B在罂粟属中为新发现。所有结构均通过光谱和物理数据确定。

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