Kemmlein Sabine, Herzke Dorte, Law Robin J
Federal Institute for Risk Assessment (BfR), Thielallee 88-92, D-14195 Berlin, Germany.
J Chromatogr A. 2009 Jan 16;1216(3):320-33. doi: 10.1016/j.chroma.2008.05.085. Epub 2008 Jun 3.
The EU REACH legislation will require the registration of 30,000 currently marketed chemicals, including the main commercial BFRs in use (Deca-BDE, HBCD and TBBP-A). Much of the data needed for registration are already available, thanks to risk assessments of continued production and use already undertaken in the EU. Within the authorisation, substitution by less hazardous chemicals is encouraged. Both qualitative and quantitative methods for the analysis of flame-retarded polymers are needed in order that the identity and concentration of the BFRs can be established and compliance with regulations including the RoHS Directive demonstrated. These are reviewed.
欧盟的《化学品注册、评估、授权和限制法规》(REACH)将要求对目前市场上销售的30000种化学品进行注册,包括正在使用的主要商用溴化阻燃剂(十溴二苯醚、六溴环十二烷和四溴双酚A)。由于欧盟已经对持续生产和使用进行了风险评估,注册所需的许多数据已经可以获取。在授权范围内,鼓励用危害较小的化学品进行替代。为了确定溴化阻燃剂的种类和浓度,并证明符合包括《限制有害物质指令》(RoHS)在内的法规要求,需要采用定性和定量方法对阻燃聚合物进行分析。本文对此进行了综述。