Takeuchi Masaki, Li Qingyang, Yang Bingcheng, Dasgupta Purnendu K, Wilde Vincent E
Department of Chemistry and Biochemistry, The University of Texas at Arlington, Arlington, TX 76019-0065, United States.
Talanta. 2008 Jul 30;76(3):617-20. doi: 10.1016/j.talanta.2008.04.001. Epub 2008 Apr 10.
A capacitance to digital converter (AD7746) is used in the same mode as noncontact conductance detectors. The detector output is linearly proportional to specific conductance (sigma) at low sigma values but becomes nonlinear and reaches a plateau value at sigma approximately >0.75 mS/cm, regardless of the nature of the electrolyte. For all applications at sub- to low-mM concentrations, the device, available as an evaluation board, provides a very affordable nothing-else-required means of contactless surrogate conductivity detection from capillary scale to larger bore conduits. For the same measurement cell volume, the detector provides virtually the same limits of detection (LODs) as a standard galvanic contact conductivity detector in conventional scale suppressed conductometric ion chromatography. The detection limits deteriorate as the conduit inner diameter decreases.
电容数字转换器(AD7746)的使用模式与非接触式电导检测器相同。在低电导率值时,检测器输出与电导率(σ)呈线性比例关系,但在电导率约>0.75 mS/cm时变为非线性并达到平稳值,与电解质的性质无关。对于所有亚毫摩尔至低毫摩尔浓度的应用,该器件以评估板形式提供,从毛细管规模到更大内径的管道,提供了一种非常经济实惠的无需其他设备的非接触式替代电导率检测方法。对于相同的测量池体积,该检测器在常规规模抑制型电导离子色谱中提供的检测限(LOD)与标准原电池接触式电导检测器几乎相同。随着管道内径减小,检测限会变差。