Yang Bingcheng, Zhang Feifang, Liang Xinmiao, Dasgupta Purnendu K, Liu Shaorong
Anal Chem. 2009 Jun 15;81(12):5102-6. doi: 10.1021/ac900570s.
We describe an electroosmotic pump (EOP) that utilizes a cation exchange resin bead as the electric field decoupler. The resin bead serves as a electrical grounding joint without fluid leakage, thus eliminating electrolytic gas interference from the flow channels. The arrangement is easy to practice from readily available components, displays a very low electrical resistance, and is capable of bearing high backpressure (at least 3200 psi). We use a silica xerogel column as the EOP element to pump water and demonstrate a complete capillary ion chromatograph (CIC), which uses a similar bead based microelectrodialytic generator (micro-EDG) to generate a KOH eluent from the pumped water. We observed good operational stability of the complete arrangement over long periods.
我们描述了一种电渗泵(EOP),它利用阳离子交换树脂珠作为电场去耦器。该树脂珠充当无流体泄漏的接地接头,从而消除了流动通道中的电解气体干扰。这种装置使用现成的组件易于实现,具有非常低的电阻,并且能够承受高背压(至少3200磅力/平方英寸)。我们使用硅胶干凝胶柱作为电渗泵元件来抽水,并展示了一种完整的毛细管离子色谱仪(CIC),该色谱仪使用类似的基于珠子的微电渗析发生器(micro-EDG)从抽水中生成氢氧化钾洗脱液。我们观察到整个装置在长时间内具有良好的运行稳定性。