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2-氨基-4-氯-6-[N-甲基-N-(4-甲基苯基)氨基]嘧啶：4,6-二取代-2-氨基嘧啶中边缘稠合R(2)2(8)环氢键链的形成与断裂

2-Amino-4-chloro-6-[N-methyl-N-(4-methylphenyl)amino]pyrimidine: formation versus fragmentation of hydrogen-bonded chains of edge-fused R(2)2(8) rings in 4,6-disubstituted 2-aminopyrimidines.

作者信息

Rodríguez Ricaurte, Nogueras Manuel, Cobo Justo, Low John N, Glidewell Christopher

机构信息

Departamento de Química Inorgánica y Orgánica, Universidad de Jaén, 23071 Jaén, Spain.

出版信息

Acta Crystallogr C. 2008 Jul;64(Pt 7):o376-8. doi: 10.1107/S0108270108016405. Epub 2008 Jun 14.

DOI:10.1107/S0108270108016405
PMID:18599981
Abstract

Molecules of the title compound, C(12)H(13)ClN(4), are linked by two independent N-H...N hydrogen bonds into a chain of edge-fused R(2)(2)(8) rings. The significance of this study lies in its attempt to rationalize the patterns of supramolecular aggregation in the title compound and in a range of analogous 4,6-disubstituted 2-aminopyrimidines.

摘要

标题化合物C(12)H(13)ClN(4)的分子通过两个独立的N-H...N氢键连接成由边稠合的R(2)(2)(8)环组成的链。本研究的意义在于试图阐明标题化合物以及一系列类似的4,6-二取代2-氨基嘧啶的超分子聚集模式。

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